EH PH DIAGRAMS FOR GEOCHEMISTRY BROOKINS PDF

Printed in U. ISBN O After all, many important geochemical processes occur at time was not taken to construct diagrams containing these species. The inclusion All in all, the book contains some very useful material and is an of Eh-pH diagrams for the tare earth elements and many elements important reference for anyone with an interest in near-surface gee with only radioactive isotopes greatly expands the coverage of previous chemical processes. There is no question, however, that it could have Eh-pH summaries. Most, though not all, of the diagrams retical basis for the use of Eh-pH diagrams, and the section for each were drawn for only one activity of the dissolved element of interest element contains a short discussion of the diagram s.

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Printed in U. ISBN O After all, many important geochemical processes occur at time was not taken to construct diagrams containing these species. The inclusion All in all, the book contains some very useful material and is an of Eh-pH diagrams for the tare earth elements and many elements important reference for anyone with an interest in near-surface gee with only radioactive isotopes greatly expands the coverage of previous chemical processes. There is no question, however, that it could have Eh-pH summaries.

Most, though not all, of the diagrams retical basis for the use of Eh-pH diagrams, and the section for each were drawn for only one activity of the dissolved element of interest element contains a short discussion of the diagram s. Much of this 10m6for most-abundant elements and s for less-abundant ele- material is so brief that it is most useful to those already familiar ments , making it difficult for the reader to get a quick idea of how with the subject, however.

The explanation of procedures for cal- relations change with changes in activities of dissolved species. It culating Eh-pH diagrams, for example, would permit only the most would have been particularly helpful to draw the S-OH and C-OH determined beginner to make a more specialized diagram. Elements diagrams, which are so important to many of the other diagrams, in are treated in the book in the order used by the U.

National Bureau a way that would illustrate not only the dominance field for each of Standards, from gases through alkali elements. Those among us ion, but also the variation in individual Sand C complex ion activities to whom this order is not second nature will have difficulty locating within dominance fields More complex but realistic systems, such elements of interest in the Table of Contents. Thus, the eager mader, who opened Index, which was found to list only 50 of the 67 elements treated in this book in search of a comprehensive depiction of Eh-pH relations the book, and to omit some minerals shown in the diagrams, including for all important natural systems, has some very worthwhile and old standards such as magnetite shown on p.

The diagrams am clearly drawn and undemtandable, although some legends and diagrams do not agree. MI

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Eh pH Diagrams for Geochemistry

The thermodynamic data for important molybdenum species are given in Table 4 t. The species MoS 2 occupies the sulfide-stable part of the diagram, and aqueous species dominate under sulfate-stable conditions, except for a small field of ilsemannite M0 30 S. Mo species in natural waters under oxidizing conditions occur as various Mo V, VI oxyions. It is transported with similar ions, i.

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